Hi and welcome to Librivox!
There are a few things to do before you get started.
You will need to complete a one minute test - this is to check your specs are up to Librivox standards, and if not, you'll be given hints on how to remedy that. http://wiki.librivox.org/index.php/1-Minute_Test
Please post your test in the Listeners Wanted forum (see the dropdown at the bottom of the page) for the speediest response. Waiting for the OK may seem tedious, but can save time in the long run.
You will also need to be added to the catalog of readers. I will add you using your forum name, but if you prefer your real name or a pseudonym let me know. We can also link to a personal blog or website. If you click on your name in any Magic Window, you will see your own personal catalog page.
Be sure to read the first post - all the info you need is there, but if anything doesn't make sense, just ask. The wiki (see the top of the page) has bundles of info too.
You can see which sections are unclaimed in the Magic Window... in the column on the right they are marked 'open'. You can request any of those. As you can see, there are quite a few open sections in this project. I would recommend a section of around 1000 words for a first recording, just to get the feel of the process. After that, go where the mood takes you
With that in mind, I am assigning section 13 to you... but if that doesn't suit, just let me know and I can unassign it and assign something else. 
Lynne
That's what I thought, so I assigned it to you.